SESSION 7
FIRE AND EXPLOSIONS
IGNITION BY LASER - IRRADIATED SURFACES
J. Adler, F.B. Carleton and F.J. Weinberg
Imperial College, London SW7 2BY
ABSTRACT
The conditions under which continuous wave laser irradiation of inert targets
leads to the ignition of a surrounding flammable gas mixture are studied in
relation to the hazard associated with the use of optical fibres in explosive
atmospheres. Results for stoichiometric mixtures in air of eleven diverse fuels
are presented in the form of minimum igniting irradiance, uniform over an area
large by comparison with quenching dimensions as a function of the time to
ignition. Thermal histories during radiant heating and cooling of the target in
an inert atmosphere are used to establish its thermal characteristics. The
variation of minimum igniting irradiance with ignition lag is universally such
that the igniting energy density varies linearly with time - a relationship
which is accounted for theoretically. The intercept gives the limit of minimum
igniting energy surface density as time tends to zero, whilst the slope provides
an accurate value of the minimum igniting irradiance at infinite time, from
which the surface ignition temperature can be deduced. These temperatures are
comparable to auto-ignition temperatures for rapidly reacting mixtures but
greatly in excess of them when auto-ignition temperatures are low. This is
accounted for theoretically in terms of the effect of natural convection and
empirical correlations are proposed which allow surface ignition temperatures
and hence minimum igniting irradiances to be estimated in terms of known
combustion parameters. Conversely, these relationships may be applied to deduce
unknown autoignition temperatures from our irradiance measurements and this is
applied to calculating autoignition temperatures for mixtures of fuels, with
some interesting results.
A MULTIPHASE MODELLING OF REVERSE COMBUSTION IN A FUEL BED
D. Morvanl, B. Porterie2, M. Larini2 and J.C. Loraud2
1IRPHE UMR CNRS 6594 60 rue J. Curie
2IUSTI UMR CNRS 6595 5 rue E. Fermi,
Technopole de Château Gombert,
13453 Marseille cedex 13 France
ABSTRACT
To study the basic mechanisms which govern the fire spread in heterogeneous fuel
beds, a one dimensional numerical model based on a multiphase approach is
proposed. The configuration studied reproduces a reverse combustion experiment
which represents a simplifying situation including the main physical phenomena
occurring in the development and the propagation of a surface fire. The
evolutions of state variables in the gas and solid phases are calculated
separately using a multiphase approach including interaction terms between the
two phases. The set of partial differential equations which governs the physical
behavior of the multiphase flow is solved using an accurate finite volume method
along with an adaptive mesh algorithm to track correctly the thin region where
fuel thermal degradation occurs. Both oxygen-limited and fuel-limited regimes
are examined for inlet flow velocities ranging from 2 to 30 cm/s.
THE EFFECT OF OXYGEN CONCENTRATION ON THE IGNITION OF SMOLDER OF POLYURETHANE
FOAM
D.C. Walther, R.A. Anthenien+ and A.C. Fernandez-Pello
Department of Mechanical Engineering, University of California at Berkeley, Berkeley, CA 94720
+ Current Address: Air Force Research Laboratory / Propulsion Directorate, Wright-
Patterson Air Force Base, OH 45433
ABSTRACT
Experiments have been conducted to study the ignition of both forward and
opposed smolder of a high void fraction, flexible, polyurethane foam in a forced
oxidizer flow. Tests are conducted in a small scale, vertically oriented,
combustion chamber with supporting instrumentation. A Nichrome wire heater
placed between two porous ceramic disks, one of which is in. complete contact
with the foam surface, is used to supply the necessary power to ignite and
sustain a smolder reaction. A constant power is applied to the heater for a
given period of time and the resulting smolder is monitored to extinction. The
gaseous oxidizer, metered via mass flow controllers, is forced through the foam
and heater. Reaction zone temperature and smolder propagation velocity are
obtained from the temperature histories of thermocouples embedded at
predetermined positions in the foam with junctions placed along the fuel
centerline. Tests are conducted with oxygen mass fractions ranging from 0.233 to
1.0 at a velocity of 0.1 mm/s during the ignition period and 0.7 or 1.0 mm/s
during the propagation period. The results show a well defined smolder ignition
regime primarily determined by two parameters: igniter heat flux, and the time
the igniter is powered. The ignition regime is shifted to shorter times for a
given igniter heat flux with increasing oxygen mass fraction. An additional
requirement for ignition is that the fuel igniter interface must attain a
minimum temperature. An energy balance model has been developed that well
describes the observed ignition results. The model is based on the assumption
that for ignition to occur the heater must provide a heat flux equivalent to a
propagating smolder front at a given distance from the igniter.
Melissa K. Anderson, Randall T. Sleight and Jose L. Torero
Department of Fire Protection Engineering,
University of Maryland College Park, MD20742-3031 USA
ABSTRACT
An experimental study has been conducted to determine signatures that will
describe the onset of self-sustained downward smolder. The fuel used is
polyurethane foam, mainly due to its common occurrence in households and thus
its importance in fire scenarios linked with smoldering combustion. The
polyurethane foam is subject to a constant heat flux imposed by a cone heater
for different time periods. Temperature and mass loss rate measurements together
with visual observations serve to determine serve to determine specific events
that can be considered signatures of the onset of a self-sustained smolder
reaction. There stages were identified in the ignition process: the warm-up
stage and unsteady smolder stage, both controlled by external heat flux; and the
self-sustained smoldering stage controlled by the heat generation by the smolder
reaction. Each stage is characterized by a change in the signatures of
temperature history and mass loss rate. It was observed that self-sustained
smolder could only occur in an external heat flux window (6.1 kW/m2 < q"e < 6.8
kW/m2). A minimum duration of exposure, weakly dependent on the external heat
flux, was also found. These observations agree well with previously reported
work. A minimum temperature (575 K < Tc < 600 K) was found necessary for
sustained smoldering combustion.
EXTINCTION LIMITS OF OPPOSED JET TURBULENT PREMIXED METHANE AIR FLAMES WITH
SPRAYS OF WATER AND NaCl-WATER SOLUTION
B. Mesli and I. Gokalp
Laboratoire de Combustion et Systémes Réactifs,
Centre National de la Recherche Scientifique, 45071 Orleans Cedex 2, France
ABSTRACT
An experimental study on water mist extinction of turbulent premixed flames is
described. The aim of the study is to compare the extinction limits of opposed
jet turbulent methane/air flames with and without the addition of water mist,
and to study the influence of several parameters including the structure of
water mist in terms of droplet size and mass fraction of the condensed phase,
mean strain rate and equivalence ratio. The effect of NaCl water solution on
premixed flame extinction is also presented. An existing opposed jet turbulent
premixed flame experimental set-up is modified to include a water mist
production system. An air assisted atomizer is developed to produce and control
the water mist. The structure of the water mist is characterized by a Phase
Doppler Anemometer. Water mist interaction with three different configurations
of the opposed jet premixed flames is explored and the results are discussed by
introducing a parameter representing the water mist efficiency.
KEYWORDS: Water mist, Flame extinction, Turbulent premixed flames
EFFECT OF PILE HEIGHT ON SPONTANEOUS HEATING OF COAL STOCKPILES
Ahmet Arisoy* and Fehmi Akgun**
* Technical University of Istanbul, Faculty of Mech. Eng., Gumussuyu, Istanbul,
Turkey
**Division of Energy Systems, Marmara Research Centre, P.O. Box 21, Gebze,
Kocaeli, Turkey
ABSTRACT
The purpose of this study is to predict the safe storage height of coal
stockpiles. To accomplish this, a one-dimensional non-steady-state model with
the effect of stockpile height approximated by a heat sink in the one-
dimensional energy equation has been developed. The model consists of
conservation equa6ons for oxygen, water vapour, inherent moisture of the coal,
and energy for both gaseous and solid phases. The heat sink term taken from
literature is based on an assumed sinusoidal variation in temperature in the
vertical direction.
Numerical solution of the model equations gives the time-dependent maximum
temperature in the coal stockpile. The effect of stockpile height on the maximum
temperature has been analysed parametrically for four different low-rank Turkish
coals. When the safe storage time is specified, the critical height can be
determined. By defining the storage time as three months it has been found that
these critical values varied between 0.85 and 1.8 m depending on the liability
of the coals to spontaneous heating.
PRELIMINARY EXPERIMENTAL INVESTIGATION OF THE PRESSURE EVOLUTION IN DETONATION
CELLS
M. Hanana1, M.H. Lefebvre2, P. Van Tiggelen
Laboratoire de Physico-Chimie de la Combustion, Universite Catholique de Louvain - Louvain-la-Neuve - Belgium
1Institut de Mecanique, Universite de Blida, Blida, Algeria
2Dept. of Chemistry, Royal Military Academy, Brussels, Belgium
ABSTRACT
Recently two types of 3D structure of gaseous detonation have been documented:
rectangular and diagonal modes, easily distinguishable from soot records. This
paper presents pressure measurements recorded along the central axis of the
cellular structure. The pressure records are achieved by using piezoelectric
gauges flush-mounted with respect to the surface of the soot covered plate
located in the detonation tube. The low pressure reactive mixture used (H2, O2,
Ar, Equivalence Ratio = 1) is ignited in a square cross-section tube. The
detonation tube is operated in the shock tube mode. The time evalution of the
local pressure exhibits several pressure peaks depending on the type of 3D
structure and on the position in the detonation cell. The first peak
characterizes the leading shock and the subsequent pulses correspond to the
elaborate shock structure. The influence of the slapping waves is documented.
The pressure profiles throughout the whole length of the detonation cell is
reported for the individual types of 3D structure. The second pressure jumps can
be rationalized in terms of the classical transverse waves structure and will be
discussed.
THE PREDICTION OF TURBULENT FLAME ACCELERATION IN OBSTACLE FILLED TUBES
M.Maremonti1, G.Russo2, E.Salzano3, J.H.S. Lee4
1Dipartimento di Processi Chimici dell'Ingnegneria, Universitâ di Padova,
Italy
2CNR-Istituto di Ricerche sulla Combustione, Napoli, Italy
3CNR-GNDRCIE, Napoli, Italy
4Department of Mechanical Engineering, McGill University, Montreal, Canada
ABSTRACT
It is well established that rapid flame acceleration can be achieved in an
obstacle filled tube.
Depending on the fuel, mixture composition, tube diameter and obstacle
configuration, the flame eventually accelerates to steady state velocities that
range from tens to hundreds of meters per second and transition to "quasi-
detonation" or C-J detonation can also occur for sensitive mixtures. The
principle mechanism for this flame acceleration is due to the turbulence in the
unburned gas and the obstacles provide a powerful means of "randomization" of
the mean flow kinetic energy. Interaction of the flame with the obstacles also
promotes strong mixing and hence rapid combustion in the turbulent flame zone.
Due to the importance of this flame acceleration mechanism due to obstacles in.
an industrial environment and in congested offshore oil platform configurations,
a number of computer codes have been developed for predicting the pressure
profiles generated. These codes, however, have to be "validated" against
experiments of up to full scale geometry in order to acquire confidence in their
application.
In this study the "Autoreagas" code, where the turbulence is modelled by k-e
type of model, is used to predict the turbulent flame speed achieved with
different fuels in obstacle filled tubes of various diameters.
By comparing the code predictions with experimental data, some insight into the
code accuracy can be determined. In particular the results obtained showed that
the code is quite adequate in predicting the explosion behavior of
stoichiometric methane- and propane-air mixtures. However, numerical convergence
problems are encountered in the computation for off stoichiometric mixtures. The
code also failed for highly reactive gas such as acetylene and hydrogen,
particularly when adopting too refined a computational grid. The peak
overpressures generated by large-scale explosions, however, can be reproduced
with a good level of accuracy.
NUMERICAL STUDY OF UNSTEADY BEHAVIOUR OF A BUOYANT FIRE
D. Morvan1, B. Porterie2 and J.C. Loraud2
1IRPHE UMR CNRS 6594 60 rue J.
Curie
2IUSTI UMR CNRS 6595 5 rue E. Fermi Technopole de Château Gombert
13453 Marseille cedex 13 FRANCE
ABSTRACT
The unsteady behavior of a buoyant methane diffusion flame is simulated
numerically. The turbulent reactive mixture is evaluated using a RNG k-e-g
turbulence modeling and a presumed shape (b-function) pdf approach. Radiation
is considered via a differential Pl-approximation to calculate the irradiance
field and the radiative flux. To obtain an accurate description of the unsteady
behavior of buoyant diffusion flames, a Finite-Volume method including a high-
order upwind convective scheme (Quick Scheme} with a flux limiter technique
(Ultra Sharp method) and a second-order backward Euler scheme for time
integration is used. The numerical results show that the buoyant flow above the
flame is characterized by the development of large eddies on both sides of the
column formed during the expansion of the hot gases. The symmetry broken of the
flow pattern and the unsteady behavior of the flame which pulses vertically are
observed.
CFD ANALYSIS OF GAS EXPLOSIONS IN TUNNELS
P.Ciambelli1, A.Bucciero2, M.Maremonti3, E.Salzano4
1Dipartimento di Ingegneria Chimica e Alimentare, Universitâ di Salerno, Italy
2EniChem S.P.A., S.Donato Milanese (Milano), Italy
3Dipartimento di Processi Chimici dell'Ingegneria, Universitâ di Padova, Italy
4CNR-GNDRCIE, Napoli, Italy
ABSTRACT
In view of their particular geometry, road and rail tunnels have to be regarded as sites of major risk of devastating explosions. Therefore, appropriate design criteria and safety assessment procedures should be adopted for prevention purposes. However, only a few indications exist in the literature, due to the limited experimental results available at present on similar configurations.
Computational Fluid Dynamic (CFD) codes represent a suitable approach to this problem. Indeed, specific CFD codes have been developed, which are able to predict the pressure profiles generated during gas explosions in large-scale environments and in the presence of high obstacle congestion.
In this work, the Autoreagas code is used to predict the pressure, the blast wave propagation and the flame speed achieved in road and rail tunnels when varying the level of congestion and the amount of released fuel. Obtained results show that severe consequences can derive from the explosion of gas clouds in such environments, even if the fuel amount is relatively small, as that contained in a car tank.
FIRE INITIATION AND SPREAD IN OVERLOADED COMMUNICATION SYSTEM CABLE TRAYS
Norman Alvares
Fire Science Applications
Carlos Fernandez-Pello
Department of Mechanical Engineering,
University of California at Berkeley
ABSTRACT
Industrial ares originating in cable arrays are not common; but when they do
occur, they can result in economic losses that far exceed the physical damage
caused by the fire. This is particularly true for fires in telecommunication
systems, where Central Offices necessarily contain enormous arrays of cables
which are supported in multiple levels of elevated cable trays that are
distributed throughout the facility. The insulation and protective covers most
cables are combustible and the surface to volume ratio of the fuel array is
typical of close packed cribs. In this paper an analysis is presented that was
developed to describe fire growth that occurred in a Telecommunication Central
Office fire, initiating at an intersection of cable trays in the toll terminal
area. Though the building contained a complete fire detection system, the time
between the first recorded fire alarm and notification of the local fire
department was extensively delayed because of weather problems and
misinterpreted signals. The building was not sprinkler protected. Consequently,
the fire persisted for an extensive period of time. The heaviest fire damage
involved an area of only 110 m2, but because of the local cable density in this
area, the smoke and combustion gases caused potentially irreversible damage to
telephone systems throughout the floor of origin.
The analysis developed here uses available test data on cable burning in a
simplified model of fire development to predict the characteristics of the
actual fire. These characteristics include: fuel burning and heat release rates,
smoke and HCL generation, growth of the smoke layer, smoke and HCL concentration
in the layer, smoke detector activation and sprinkler actuation. The results of
the analysis are then used to estimate how alternate countermeasures could have
effected the outcome of the initiating fire. This simple, empirically driven
analytical model is sensitive to local conditions, fuel geometry and fuel
composition.
COMBUSTION BEHAVIOR OF STRATIFIED PROPANE/AIR LAYERS
SIMULATING FLAMMABLE LIQUID SPILLS
Francesco Tamanini and Jeffrey L. Chaffee
Factory Mutual Research Corporation,
Norwood, Massachusetts 02062
ABSTRACT
Testing was carried out in a 63.7-m3 chamber (4.57 by 4.57 by 3.05-m high) with
stratified mixtures of propane in air, under both vented and unvented
conditions. The tests are part of a program designed to quantify the explosion
hazard from flammable liquid spills in industrial process and dispensing areas.
Layers were formed by slowly injecting propane at the chamber floor through
diffusers, at a rate of the order of the estimated rate of vaporization of a
typical solvent such as acetone. The gas composition field was characterized
through time-resolved concentration measurements obtained at twelve locations in
the room. This was achieved using a single continuous analyzer receiving gas
samples through a multiplexing valve. Several composition profiles were
simulated, including layers in which the concentration of propane at the floor
was above the upper explosive limit (UEL). The paper presents a discussion of
the combustion behavior of the mixture following ignition. Estimates of the
burning velocity are in substantial agreement with the results from previous
works, which show that flame propagation velocities over stratified layers can
be 3-5 times the fundamental burning velocity in a mixture of near-
stoichiometric composition. A change in the internal geometry of the chamber was
introduced to study the effect of blockages on the development of the explosion.
These obstacles were found to increase the propagation velocity by about 50%
over the values observed in the empty enclosure. The paper also discusses the
role played in the process by the portion of the layer above the UEL, since this
can be a significant contributor to the pressure development in the enclosure
under certain accident scenarios.
EXPERIMENTAL AND NUMERICAL STUDY OF FLAMMABILITY LIMITS OF GASEOUS MIXTURES IN
POROUS MEDIA
L. di Mare1, T.A. Mihalik2, G. Continillo3, and J.H.S. Lee2
1Dipartimento di Ingegneria Chimica, Universitâ di Napoli Federico II,
Naples, Italy
2Department of Mechanical Engineering, McGill University, Montreal,
Canada
3Facoltâ di Ingegneria, Universitâ del Sannio, Benevento, Italy and
Istituto di Ricerche sulla Combustione CNR, Naples, Italy
ABSTRACT
The present work deals with an experimental and numerical study of flammability
limits for hydrocarbon-air mixtures in porous media and their dependence on the
physical and geometrical properties of the solid phase. Experimental data have
been obtained in a standard flammability apparatus modified through the
insertion of a packed bed of spheres. Numerical data have been obtained through
integration of the equations of a one-dimensional model with single step
kinetics. The model accounts for heat transfer to the solid phase in the porous
medium. The kinetic parameters of the model are tuned in order to match
flammability limits for freely propagating deflagrations; then, the model is
applied to cases' with porous medium. Numerical results are compared with
experimental results and at least qualitative agreement is found. Particularly,
both sets of data show that flammability limits are more sensitive to the
geometric properties of the porous medium than to its physical properties. An
explanation is given through the analysis of the heat transfer process. The
results show that, in modelling flammability limits within porous media, heat
losses to the solid phase should be taken into account along with fluid-dynamic
effects, to correctly understand extinction mechanisms and predict flammability
data.
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